I'd recommend the NY Thruway (I87) to Garden State Parkway to NJ Turnpike (I95), then south on I95 from there. There are a few ways to get to I87 from Sugarbush, the easiest likely being Vt 100 south to Killington, then Vt 4 west into Rutland and continuing west on Vt 4 to the NY border, where you pick up NY 4 west, take that through Whitehall and on to Fort Ann, where you pick up NY 149W to Queensbury and I87.
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